You can withdraw money at any time as long as each withdrawal is a minimum of €1 euro and you have enough in your account balance to cover any relevant transaction fees. For more information on this read our article on the minimum withdrawal limit.
Once you have set up a withdrawal method, make sure that it is selected in the drop-down menu, then enter the amount that you want to withdraw followed by your Spinnup password.
It normally takes 3-5 business days before the money reaches your account.